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The supercritical fluid extraction of peat using water and aqueous organic solutions

✍ Scribed by Warren P. Scarrah; Kenneth L. Myklebust Jr.


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
361 KB
Volume
65
Category
Article
ISSN
0016-2361

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✦ Synopsis


The supercritical fluid extraction of organics from sun-and air-dried peat was investigated using solvents providing different intermolecular solutesolvent forces. Snyder's classification of selectivity groups indicated that acetone-water mixtures capable of large dipole interactions were more successful than those promoting hydrogen-bonding:

water (proton donor) and methanol-water mixtures (proton acceptor). Neither solvent densities nor Hildebrand solubility parameters were satisfactory for predicting supercritical solvent effectiveness. At slightly subcritical conditions, both the acetone-water mixtures and methanol-water mixtures were good solvents.


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