A true solventless off-line supercritical fluid extraction SFE method has been developed, which does not use organic solvents for trapping and for washing out of analytes. Determination of polynuclear aromatic hydrocarbons, chlorinated pesticides, and polychlorinated biphenyls in aqueous solutions b
The supercritical fluid extraction of peat using water and aqueous organic solutions
β Scribed by Warren P. Scarrah; Kenneth L. Myklebust Jr.
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 361 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0016-2361
No coin nor oath required. For personal study only.
β¦ Synopsis
The supercritical fluid extraction of organics from sun-and air-dried peat was investigated using solvents providing different intermolecular solutesolvent forces. Snyder's classification of selectivity groups indicated that acetone-water mixtures capable of large dipole interactions were more successful than those promoting hydrogen-bonding:
water (proton donor) and methanol-water mixtures (proton acceptor). Neither solvent densities nor Hildebrand solubility parameters were satisfactory for predicting supercritical solvent effectiveness. At slightly subcritical conditions, both the acetone-water mixtures and methanol-water mixtures were good solvents.
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## Abstract Supercritical fluid extraction (SFE) of the volatile oil from __Satureja montana__ L. was performed under different conditions of pressure (90 and 100 bar), temperature (40 and 50Β°C), mean particle sizes (0.4, 0.6 and 0.8 mm) and CO~2~ flow rate (0.8, 1.1 and 1.3 kg/h) to understand the