## Abstract The dissociation of protonated alkyl benzoates (para H, CN, OMe and NO~2~) into protonated benzoic acids and alkyl cations was studied in the gas phase. It was found that the product ratio depends on the substituent at the para position of the phenyl ring. The substituent effect is prob
โฆ LIBER โฆ
The substituent effect in the fragmentation of phenylcyclohexanols
โ Scribed by F. De Angelis; M. L. Forcellese; A. Gambacorta; R. Nicoletti
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 378 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1076-5174
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## Abstract Loss of HCN from the molecular ion of benzaldoximes occurs via two distinct involving a 4โmembered and a 5โmembered intermediate, respectively. Both low energy high energy molecular ion decomposition were investigated by means of metastable peak shapes and the energetics of further deco