𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The study of intramolecular free radical cyclization of α-sulfenyl radical

✍ Scribed by Yeun-Min Tsai; Fu-Chang Chang; Jimin Huang; Chi-Lung Shiu

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
308 KB
Volume
30
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

e-Sulfenyl radical can be generated from a-chlorosulfide or dithioacetal. The olefin substituent effect on the intramolecular radical cyclization of this type was studied.

📜 SIMILAR VOLUMES

Radical cyclizations of bromo acylsilane
Radical cyclizations of bromo acylsilanes and intramolecular trapping of the rearranged α-silyloxy radicals
✍ Yeun-Min Tsai; Kuo-Hsiang Tang; Weir-Torn Jiaang 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 261 KB

Radical 1.5e.w cyclizations of acylsilanes involving secondary radicals am quite effective. In contrast, 1.6~~ cycliiions are more. sensitive toward steric effect. Tandem radical cycliioa process can be designed. Recently we reported a novel reaction involving addition of primary radicals to the ca

Free-radical Cyclization of Petroselinic
Free-radical Cyclization of Petroselinic Acid
✍ Metzger, Jürgen O. ;Mahler, Ralf 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB

## Abstract Petroselinic acid was cyclized via methyl 2‐iodopetroselinate (1) with tributyltin hydride to give methyl __trans__‐ and __cis__‐2‐dodecyl‐1‐cyclopentanecarboxylate (2). The atom‐transfer method with hexabutylditin resulted in the formation of bicyclic γ‐lactones 4 and methyl __trans__‐