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The Structures of Three [2.2]Paracyclophane Derivatives with Anellated Four-Membered Rings

✍ Scribed by Henning Hopf; Heino Hinrichs; Ludger Ernst; Peter G. Jones; Virgil Boekelheide


Book ID
112101963
Publisher
Laser Pages Publishing Ltd.
Year
2012
Tongue
English
Weight
825 KB
Volume
52
Category
Article
ISSN
0021-2148

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Helical primary structures of four-membe
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The synthesis of (M)-trispiro[3.0.0.3.2.2]tridecane [(M)-4], the first hydrocarbon with a helical primary structure of fourmembered rings, is described. Key step is the kinetic resolution of a cyclobutanone through reduction with bakers' yeast. As compared to its analogue of three-membered rings, (M