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The structures of the η-carbides Ni6Mo6C, Co6Mo6C, and Co6Mo6C2

✍ Scribed by J.M. Newsam; A.J. Jacobson; L.E. McCandlish; R.S. Polizzotti

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
612 KB
Volume
75
Category
Article
ISSN
0022-4596

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The hexacarbide clusters [H 6-n Ni 38 C 6 (CO) 42 ] n-(n = 3, 4, 5, found previously in [HNi 38 C 6 (CO) 42 ] 5-, and shows very close interatomic separations. Both [Ni 32 C 6 (CO) 36 ] 6-and [H 6- or 6) have been directly obtained from the reaction of [Ni 6 -(CO) 12 ] 2-with C 3 Cl 6 , whereas the