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The structures of 9-cis-retinal and 19,19,19-trifluoro-9-cis-retinal

โœ Scribed by Simmons, C. J. ;Asato, A. E. ;Denny, M. ;Liu, R. S. H.

Book ID
114503432
Publisher
International Union of Crystallography
Year
1986
Tongue
English
Weight
718 KB
Volume
42
Category
Article
ISSN
0108-2701

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โœ Achla Trehan; R.S.H. Liu ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 259 KB

A modified 15 + 5 route led to 7-cts.9-cis.ll-cts-retinonitrile in high selectivity and also a lesser amount of all-cis-retinonitrile. DIBAL reduction Save the corresponding retinal isomers. The absorption maximum (2S7nm) of all-&s-retinal reveals the distorted nature of the chromophore.