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The structure of β-tungsten hexachloride by powder neutron and X-ray diffraction

✍ Scribed by Taylor, J. C. ;Wilson, P. W.

Book ID
117858887
Publisher
International Union of Crystallography
Year
1974
Weight
524 KB
Volume
30
Category
Article
ISSN
0567-7408

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3-SrRh204 , a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO3 with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) A and c = 11.3996(7) A. The structure consists of CdI2-type layers of edge sharing RhO6 octahedra with