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The structure of α-ferrocenyl carbonium ions

✍ Scribed by R.G. Sutherland; J.R. Sutton; W.M. Horspool

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
158 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

The stability of 3-ferrocenylcarboniums and the stereoselectivity of their reactions No. 35

📜 SIMILAR VOLUMES

Direct observation of a 1,1′-di-α-ferroc
Direct observation of a 1,1′-di-α-ferrocenyl carbonium ion
✍ Charles U. Pittman Jr. 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 211 KB

Carbonium ions generated alpha to the ferrocene group are exceptionally stable. This has been demonstrated by the ready dehydration of 1-ferrocenylethanol to vinyl ferrocene,' by the ease of addition of weak acids (such as acetic acid and hydrogen aride) to vinyl ferrocene, 2