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The Structure of Vinyl Polymers: the Polymer from Methyl Vinyl Ketone

✍ Scribed by Marvel, C. S.; Levesque, Charles L.


Book ID
126285549
Publisher
American Chemical Society
Year
1938
Tongue
English
Weight
519 KB
Volume
60
Category
Article
ISSN
0002-7863

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2-Hydroxymethyl-but-1-ene-3-one [␣-hydroxymethyl methyl vinyl ketone (HMVK)] was synthesized from methyl vinyl ketone using paraformaldehyde and a tertiary amine catalyst. Free-radical polymerization of this monomer created transparent, tough polymers that were insoluble in organic solvents. HMVK wa