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The structure of trisformamidomethane in dimethyl sulphoxide-d6, hexamethylphos-phortriamide and trifluoroacetic acid

✍ Scribed by W. L. F. Armarego; Toshihiko Kobayashi

Publisher: John Wiley and Sons
Year: 1970
Tongue: English
Weight: 294 KB
Volume: 2
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270020205

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✦ Synopsis

Abstract

The PMR spectrum of trisformamidomethane in dimethyl sulphoxide‐d~6~ and hexamethyl‐phosphortriamide has been explained by postulating four major structures in solution: two rotamers and two structural isomers, all of which are stabilized by intramolecular hydrogen bonding to form six membered rings. The spectrum in trifluoroacetic acid is also described.

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