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The structure of trans-1,4-diisocyanocyclohexane in solution, in the solid state, and as a ligand bridging bulky tungsten(II) complexes

✍ Scribed by Thomas M. Lane; Desiree S. Grubisha; Cuie Hu; Dennis W. Bennett

Book ID: 107807171
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 1009 KB
Volume: 328
Category: Article
ISSN: 0022-2860
DOI: 10.1016/0022-2860(94)08387-8

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## Abstract The template condensation of [Cu(3, 2, 3‐tet)]^2+^ (3, 2, 3‐tet = __N__, __N__″)‐(ethane‐1, 2‐diyl)propane‐1, 3‐diamine with CH~2~O and en (en = ethane‐1, 2‐diamine) affords the copper(II) compounds of two isomeric tricyclic ligands in high yield. The strikingly different UV/VIS and EPR