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The structure of the singlet tetramethylene diradical intermediate

✍ Scribed by Fernando Bernardi; Andrea Bottoni; Glauco Tonachini; Michael A. Robb; H.Bernhard Schlegel


Book ID
103024457
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
201 KB
Volume
108
Category
Article
ISSN
0009-2614

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Arguments are presented which show that zwitterionic or diradical intermediates in the singlet oxygen-olefin ene reaction would lead to a prediction that geminal groups would be competitive in the C-H abstraction reaction. Isotope effect data available from previous studies clearly show that such is