The structure of the halides and oxides of the 5th, 6th and 7th groups

✍ Scribed by Prideaux, E. B. R.

• Book ID: 102323560
• Publisher: Wiley (John Wiley & Sons)
• Year: 1923
• Weight: 338 KB
• Volume: 42
• Category: Article
• ISSN: 0368-4075
• DOI: 10.1002/jctb.5000422702

✦ Synopsis

By tlic c:irlicr clcctroiiic tlicorics of valcncy which coiitiiiiictl 011ly the iden of clcctro\*itlt>iicy. or the p S S " g e of ill1 clcclroIl fro111 olle iltolll 1.) nllother, tile Iligllcr -nlcwt colll~'o"lltls of tile clclllcllts of tile 4111 to tile 7th gro"1's \Vcr(! S U C l l coIll~'l"lll~ls :is 1'C15 :lilt1 I'OCI, the pllos-.

nnturiilly rcprcwntcvl i i i tlic siiiiic wiy :is tlic salts of tlic 1st to tlic 3rd groiips. 'I'lius iii plioriis, :is tlic 1110rc clcctro-positi-c clciiiciit, wis coiisitlc.rctl to 1i:ivc lost 5 vlcctrons t.1 tlic chloriiit., etc. Such :in itleit is iiot cscliitletl l)y liitcr tltcorir.~, aiirl in the conipoiiiids o f tlic noii-iiictnls with fluoriiic, osygcii, clilorinc which csliihit the iii:isiiiiuiii typiciil or groirp stripping its slicntli. Such coiiipoiin(1s do iiot sliow cvitlciice of clcctrolytic tlissociiitioii, but this iiiiglit bc iiccouiitctl for, on tlic oiic liniitl, by tlic difficulty of opciiiiig i i p strong closet1 ficlds of force (n tlilliculty which is :rlrc;itly