The structure of the five-membered cyclic sultone 9,10-dihydro-10a-methyl-3a,9-methano-3H-benzo[5,6]cyclohept[1,2-d][1,2]oxathiol-4(3aH)-one dioxide, C14H14O4S
✍ Scribed by Brown, D. S. ;Heaney, H. ;Mason, K. G.
- Book ID
- 114502088
- Publisher
- International Union of Crystallography
- Year
- 1984
- Tongue
- English
- Weight
- 293 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Two coordination polymers 1 ϱ {[Cd(phen)](C 6 H 8 O 4 ) 3/3 } (1) and 1 ϱ {[Cd(phen)](C 7 H 10 O 4 ) 3/3 } • 2H 2 O (2) were structurally characterized by single crystal X-ray diffraction methods. In 1 (C2/ c (no. 15), a ϭ 16.169(2) A ˚, b ϭ 15.485(2) A ˚, c ϭ 14.044(2) A ˚, β ϭ 112.701(8)°, U ϭ 324
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.