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The Structure of the D. gigas [NiFe] Hydrogenase and the Nature of the Hydrogenase Nickel Complex

✍ Scribed by Dr. Malcolm A. Halcrow


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
345 KB
Volume
34
Category
Article
ISSN
0044-8249

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In this review a historic overview is given of the biomimetic models synthesised since the presence of nickel in hydrogenases was first reported in 1981. The crystal structure of the [NiFe] hydrogenase isolated from Desulvofibrio gigas unexpectedly revealed a heterodinuclear active site, including a