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The structure of the CFCl3 radical anion

✍ Scribed by L. Bonazzola; J.-P. Michaut; J. Roncin

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 349 KB
Volume: 149
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)85033-4

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✦ Synopsis

Exposure of trichlorofluoromethane in the presence of tetrahydropyran or some other impurities at very low concentration to @'Coy rays at 77 K gives the CFCI, radical anion. From the analysis of its EPR spectrum and from ab initio geometry optimization, it is concluded that the anion has CJ, symmetry.

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## Abstract ESR. and ENDOR. studies are reported for the radical anions of 1,2‐diphenylcyclopentene (**3**) and its di(pe+deuteriophenyl)‐derivative (3‐D~10~). Comparison of the coupling constants of the phenyl protons in **3**\documentclass{article}\pagestyle{empty}\begin{document}$ ^{\ominus \ato