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The structure of the C2H2+4 dication

✍ Scribed by Ross H. Nobes; Ming Wah Wong; Leo Radom

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 321 KB
Volume: 136
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80255-5

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✦ Synopsis

High-level ab initio molecular-orbital calculations indicate that the only C2H4 2+ isomer likely to be observable in the gas phase is the perpendicular ethylene dication (1). Other C,H:+ isomers lie higher in energy with extremely small barriers for collapse to 1.

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