The structure of tetraaqua(2,2,3,3-tetrafluorosuccinato)zinc(II)
β Scribed by Karipides, A.
- Book ID
- 119771443
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 436 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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π SIMILAR VOLUMES
The barium cation in the centrosymmetric title compound, [Ba 2 (C 5 H 2 N 3 O 5 ) 4 (H 2 O) 8 ], is in a ten-coordinate environment with two anionic ligands and four water molecules. The Ba-O bond distances lie in the range 2.723 (2)-3.260 (2) A Λ. The deprotonated O atom of the ligand bridges the B
The Co II ion in the title compound, [Co(C 5 H 2 N 2 O 4 )(H 2 O) 4 ]Γ-2.5H 2 O, is chelated by the orotate dianion through carboxylate O and pyrimidine N atoms, and its octahedral geometry is completed by four water molecules. An intermolecular N-HΓ Γ ΓO hydrogen bond forms an orotate-orotate dimer