The structure of some antibiotics from the sponge ircinia strobilina
β Scribed by Irvin Rothberg; Peter Shubiak
- Book ID
- 104213521
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 212 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Four related sesterterpenes, which contain one or more furan rings and a tetronic acid moiety, have been isolated from sponges of the genus Ircinia. 1.2
We wish to report the isolation and structure elucidation' of a new sesterterpene, strobilinin 1 which coexists with variabilin $_ in the sponge Ircinia m strobilina.
π SIMILAR VOLUMES
The absolute configuration of halisulfate 3 (1), a metabolite of the sponge Ircinia sp. from the Philippines, was determined in two steps. The (13S) absolute configuration was derived by application of the chiral amide method using acid 5. The (8R.9S) stereochemistry of the bicyclic ring system was