Novel cationic allylpalladium(II) complexes containing the alkaloid (-)-sparteine (1) as a bidentate ligand have been prepared. Two of them, [q3-(cyclohex-2-enyl)] (sparteine)palladium(II) hexafluorophosphate ([Pd(v3-C6H,)(sparteine)][PF6]; 3b) and (sparteine)[~3-(1,1,3-triphenylallyl)]palladium(II)
✦ LIBER ✦
The structure of novel cryptands containing metallocene units by polarisation transfer sequences and 2-D NMR
✍ Scribed by Paul D. Beer; Jane Elliot; Philip J. Hammond; Clare Dudman; C.Dennis Hall
- Book ID
- 103224666
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 321 KB
- Volume
- 263
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The determination of the structure of {[5‐__O__‐(__E__)‐feruloyl] [__O__‐β‐D ‐xylopyranosyl‐(1 → 2)]‐__O__‐α‐L arabinofuranosyl‐(1 → 3)}‐__O__‐β‐D‐xylopyranosyl‐(1 → 4)‐D‐xylopyranose, a compound isolated from the cell walls of Gramineae, is presented. Use is made of 1D HOHAHA and 2D ^1
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