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The structure of HSSi+ as determined by fourth-order many-body perturbation theory

✍ Scribed by Eneida G. Lima; Sylvio Canuto

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
299 KB
Volume
144
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rotational constants of HSSi+ and HSiS+ are calculated by fourth-order many-body perturbation theory utilizing a doublezeta plus polarization basis set. The results agree with a previous CI estimate that HSSi+ (bent) is more stable than HSW (linear) and frequencies of rotational lines are predicted for possible astrophysical identification.

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