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The structure of dispiro(tricyclo[3.3.1.13,7]decane-2,6'-6'H,12'H-dibenzo[b,f][1,5]dioxocin-12',2''-tricyclo[3.3.1.13,7]decane), C32H36O2

✍ Scribed by Garbauskas, M. F. ;Evans, I. A. ;Talley, J. J.

Book ID
114502671
Publisher
International Union of Crystallography
Year
1985
Tongue
English
Weight
342 KB
Volume
41
Category
Article
ISSN
0108-2701

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## Abstract On irradiation (300β€…nm) in the solid state, the title compound **8** affords tricyclo[3.3.1.1^3,7^]decan‐2‐one (=adamantan‐2‐one; **9**) selectively __via__ [4+2] cycloreversion. A similar result is obtained on photolysis in solution (MeCN or acetone), also in the presence of added alke