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The structure of chloro-bridged rhodium(III) complexes of tri-n-butylphosphine

✍ Scribed by F.H. Allen; K.M. Gabuji


Publisher
Elsevier Science
Year
1971
Weight
100 KB
Volume
7
Category
Article
ISSN
0020-1650

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The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice