## Abstract The revised structure **1** is put forward for peduncularine, the main alkaloid of __Aristotelia peduncularis__ (Labill.) HOOK. F. (__Elaeocarpaceae__), on the basis of its spectroscopic properties and those of its degradation products, the __Hofmann__ base **3** and the hydrogenation p
β¦ LIBER β¦
The Structure of C-Alkaloid-O, a Constituent of Calabash Curare. Part 187. Papers on organic natural products
β Scribed by Robert P. Borris; Armin Guggisberg; Manfred Hesse
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- German
- Weight
- 362 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0018-019X
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β¦ Synopsis
Abstract
The structure of CβalkaloidβO (1=his HCLβsalt) was established on the basis of spectral data and comparison with the analogous compound 2, synthesized from a natural product of known absolute configuration. Internally consistent ^13^CβNMR. assignments are given for 1, 2, huntrabrine methochloride (4) and its diacetate derivative 5.
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