The structure of aqueous solutions
β Scribed by J.E. Enderby; W.S. Howells; R.A. Howe
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 267 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A series of neutron dIffractIon expenments has been carried out on sclutlons of NICI~. NaCl and BzC12 m hea: water Both the conccntratlon of the solute and the degree of lsotoplc ennchment were vaned or: order to mvestlpatc whether the multlple-pattern method, which has been used prevrously to determme the partlzl structure factors for ample Irqulds, can be apphed to aqueous solutions It 1s concluded that the multiple-partcrr method IS feasrbk Some general comments on the srructural mformatlon contained In the smgle-patrcrn data arc made
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The identification, by their infrared spectra, of species formed by specific interactions between water and three salts (LiC104, BrNBuOq, LiBr) leads to some understanding of the microscopic structure of salt saturated aqueous solutions. The concepts nstructure-maker~. "structure-breaker". are crit