Unequivocal phase identification of alite in portland cement clinker has been made by combined use of microscopy during heating, X-ray powder diffraction, and differential thermal analysis. Alite thus far assigned to Mlb by X-ray powder diffractometry, in reality, gives every indication of being M
The structure of alite in Portland cement clinker — TEM evidence
✍ Scribed by K.E. Hudson; G.W. Groves
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 586 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0008-8846
No coin nor oath required. For personal study only.
✦ Synopsis
In the examination of alite in Portland cement clinker by transmission electron microscopy, the dominant structure found was that described by Jeffery (I). Twinning on the pseudomirror plane of the monoclinic structure has been found. This provides an explanation for some weak extra X-ray reflections reported by Jeffery (1). A transformation to a new lattice occured when alite was heated in the electron microscope. Microstructural defects and diffraction effects not accounted for by the Jeffery lattice are discussed.
Mit einer Untersuchung mittels Durchstrahlungselektronenmikroscopie wurde es gezeigt, dass die gewohnliche Struktur yon Alite in dem Portland-Zement die yon Jeffery beschriebene (I) Struktur war. Zwillinge auf den Pseudospiegelebenen des monoklinen Kristalles gefunden wurden.
Diese Zwillinge erkl~ren schwache ausserordentliche RSntgenreflexionen, die Jeffery berichtet hatte (i). Als Afire in dem Elektronenmikroscop gew~rmt wurde, wurde eine Gitterumwandlttng beobachtet.
Kristallfehler und Beugungsbilder, die der Gitter yon Jeffery nicht erklMren kann, behandelt werden.
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