𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The structure of AgI-Ag2O-V2O5 glasses

✍ Scribed by H. Takahashi; Y. Hiki; T. Sakuma; Y. Morii

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
328 KB
Volume
90
Category
Article
ISSN
0167-2738

No coin nor oath required. For personal study only.

✦ Synopsis

Structures of lOAgI-3Ag,O-2V,O,, 3AgI-3Ag,O-2V,O, and 2AgI-2Ag,O-V,O, glasses have been investigated by neutron diffraction experiments. The characteristic features of observed structure factors S(Q) in lOAgI-3Ag,O-2V,O, glass is similar to those of other superionic conducting glasses and molten AgI. From the standpoint of the pair distribution functions, it is clarified that the Ag-I and I-I correlation strength and Ag-Ag correlation length increase with increasing AgI concentration. Observed results suggest that the local AgI structure accompanied by the re-arrangement of silver ions is formed with highly doped iodide ions.

📜 SIMILAR VOLUMES

X-ray diffraction studies on AgI-Ag2O-V2
X-ray diffraction studies on AgI-Ag2O-V2O5 glasses
✍ S. Patnaik; K. Muruganandam; M. Seshasayee; H. Ohtaki 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 353 KB

Results of X-ray diffraction studies on glasses in the AgI-Ag,O-V,O, system are presented. In these glasses, the vanadium atom adopted five-fold coordination of oxygen atoms more frequently than four-fold and six-fold and the V-O distances lay between 1.76 and 1.79 A. The VO, polyhedra in the glasse

The electrical properties of AgI−Ag2O−P2
The electrical properties of AgI−Ag2O−P2O5 glasses with high AgI content
✍ J.L. Nowiński; B. Wnętrzewski; W. Jakubowski 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 104 KB

Gla~ of corn p~iclo n xagl (I--XIA~. 02 ~X~0S were storied by ,dmit lan~ s~ro~apy. DTA, X-re r dimaOion. \*n~tcat and ~n ~n\* elca~n m [~py FOe the ~m ~,[Oon ~1~ x ~ 0.6~ the ionic ~M~i v~W ~s maxlmal ~i1r the a~i i a the fo~ ~r ~a~plr ~i~h x> 0.7 cxh~ited the same v~l~e ~ f eL and /'~ nS the gl~ wi

Ionic Conductivity of Glass-Ceramic Comp
Ionic Conductivity of Glass-Ceramic Composites in the AgI-Ag2O-V2O5 System
✍ Krasowski, K. ;Garbarczyk, J.E. ;Wasiucionek, M. 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 2 views

Electrical ionic conductivity of two families of silver-vanadate superionic glass-ceramic composites: 50 AgI Á (50 --x)Ag 2 O Á xV 2 O 5 , 14 x 25 and yAgI Á (80 --y)Ag 2 O Á 20 V 2 O 5 , 30 y 50 was studied. The composites were prepared by annealing initially amorphous samples of the above composit