✍ Scribed by K. Wiesner; M. Götz; D.L. Simmons; L.R. Fowler; F.W. Bachelor; R.F.C. Brown; G. Büchi
No coin nor oath required. For personal study only.
TRE alkaloid aconitine C3$i4,011N is the most important and aomplicated representative of the class of aconitum alkaloids. The confusing and contradictory chemical studies on aconitine before 1900 have been revlewed by Schulze.' Subsequent studies covering the first half of the 20th century, which led only to the clsxificatinn of the functional groups, have been reviewed again by Stern.' We non wish to propose the complete structure of aconitine (I) in which the only ambiguity is that a methoxyl and hydroxyl may have to exchange positions. We shall start elaborating the argument by shoving that the structure of the C-D ring system of aconitine (II) differs from the recently deduced 3 structure of the C-D ring system of delphinine (III) only by the presence of an additional hydroxyl.
📜 SIMILAR VOLUMES
bei 123 bis 125O und hat ein spec. Gewicht von 0,7032 bei 17O Cels. Es ist fdentisch mit dem Octan, erhalten aus M e t h y l -H e x y l -C a r b i n o l und mit dem von Z i n c k e aus dem primiiren Octylalkohol dargestellten. (Benkhte d. deutschen chem.