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The structure and stereochemistry of Jamine, C21H35N3, by x-ray analysis

✍ Scribed by I.L. Karle; J. Karle


Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
111 KB
Volume
4
Category
Article
ISSN
0040-4039

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✦ Synopsis


The seeds of Oaosia panamensi& Berth. sad related speoiea caataia a amber of related alkaloidsl.

Among thea is oaosaaiao, C20D3SN3, also knowa as piptaaine* and alkaloid A3. The fonaldebYde addact of C.&lsN3, which we shall designate as jraine, is identical to a aaturallY occurriag 4 alkaloid in Oaosia j~aioeasi2 . Crystals of j-in0 for ths x-ry deteraination of the molecular structure were kindlY supplied by Drs. 8. A. Llqd and P. Nregeli of the National Institutes of Health. Jaaiae occurs naturally as a racaaate, bonce it n aY be expected that the aaterial crJstalliaes in a cantrosvtric systm. It was fond


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