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The structure and stability of the dications, XH2+itn(X = N, O, P, S)

✍ Scribed by Susan A. Pope; Ian H. Hillier; Martyn F. Guest; John Kendric


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
270 KB
Volume
95
Category
Article
ISSN
0009-2614

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The structure, infrared spectrum, and heat of formation of B2N, B2N-, BO, and B20 have been studied ab initio. B2N is very stable; B20 even more so. BIN, B,N-, B20, and probably B2N+ have symmetric linear ground-state structures; for B20, an asymmetric linear structure lies about 12 kcal/mol above t