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The structure and helicity of perfluorooctanonitrile, CF3–(CF2)6–CN

✍ Scribed by W.C. Bailey; R.K. Bohn; C.T. Dewberry; G.S. Grubbs II; S.A. Cooke

Book ID
113726575
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
247 KB
Volume
270
Category
Article
ISSN
0022-2852

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The reactions of Zn(CF 3 )Br ´2 CH 3 CN, Cd(CF 3 ) 2 ´2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br ´2 CH 3 CN yields (Ndifluoromethyl)-4-N,N