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The structural vacancies in palladium hydride. Phase diagram

✍ Scribed by Svetlana Yu. Zaginaichenko; Zinaida A. Matysina; Dmitry V. Schur; Lyudmila O. Teslenko; Ayfer Veziroglu

Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
499 KB
Volume
36
Category
Article
ISSN
0360-3199

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✦ Synopsis

The theory development of structural vacancies formation in palladium hydride on the molecular-kinetic presentations is the subject of this paper. The production of vacantordered superstructure of Cu 3 Au type has been considered at the high temperatures. The calculation of free energies of the PdH and Pd 3 VH phases has been carried out. The constitution diagram defined the temperature and concentration regions of phases formation with the A1 and L1 2 structures and regions of two A1 ΓΎ L1 2 phases realization has been constructed. The results of theoretical calculations are in agreement with experimental data.

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