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The structural characteristics and mechanical behaviors of nonstoichiometric apatite coatings sintered in air atmosphere

✍ Scribed by Han, Yong ;Xu, Kewei ;Lu, Jian ;Wu, Zhu


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
371 KB
Volume
45
Category
Article
ISSN
0021-9304

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✦ Synopsis


Two types of nonstoichiometric apatite coatings on Ti6Al4V substrates were prepared in our laboratory by electrodeposition and hydrothermal synthesis. One was composed of highly pure needle-like calcium-deficient hydroxyapatite, and the other consisted of needle-like calciumdeficient hydroxyapatite and plate-like brushite. In this paper, the morphology, phase transition, and bonding strength of these coatings sintered at 450 °∼980°C in an air atmosphere were studied. In addition, the residual stresses in pure calcium-deficient hydroxyapatite coatings and coatings sintered at 800°C were measured by a hole-drilling method.

The results show that after being sintered at a higher temperature, the coating/Ti6Al4V samples exhibited structural characteristics such as biphasic [hydroxyapatite + ␤-Ca 3 (PO 4 ) 2 ] coatings and dense TiO 2 film/Ti6Al4V in which the residual stresses in the coatings slightly increased. In addition, the results indicate that bonding strength was improved.