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The Steric Inhibition of Resonance. III. 1 Acid Strengths of Some Nitro- and Cyanophenols

✍ Scribed by Wheland, G. W.; Brownell, R. M.; Mayo, E. C.

Book ID
126459171
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
548 KB
Volume
70
Category
Article
ISSN
0002-7863

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Steric Inhibition of Resonance: A Revisi
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The classical concepts of steric inhibition of resonance (SIR) and primary steric effect (van der Waals interactions) were revised with the aid of methyl-substituted benzoic acids. The quantum chemical model was based on the energies of various conformations, calculated at the RHF/6-31 +G(d,p) and B