The steric effect and enantioselectivity of chiral 2,2-disubstituted thiaprolinol derivatives as ligands for borane reduction of aromatic ketones and for diethylzinc addition to aromatic aldehydes
β Scribed by Hsiang-Ling Huang; Ya-Chuan Lin; Shyh-Fong Chen; Chia-Lin J. Wang; Lee Tai Liu
- Book ID
- 108038454
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 210 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0957-4166
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Several new chiral auxiliaries with differing steric and electronic environments, such as β£,β£Π-dimethyl-2,6-pyridinedimethanol, β£,β£Π-ditrifluoromethyl-2,6pyridinedimethanol, β£,β£Π-dipentafluoroethyl-2,6-pyridinedimethanol, and β£,β£Π-diallyl-2,6pyridinedimethanol, have been examined and compared with β£
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