Norbornadienylidene is of interest since extended calculation predicted that norbornadienylidene would have the difinitive probability of a singlet state stabilized nonclassical methylene (1). A possible &-elimination of 7-chloronorbornadiene g (2) to overcome the antiaromatic destabilization (3) of
β¦ LIBER β¦
The stereospecific ring opening rearrangement of epichlorohydrin with n-butyllithium
β Scribed by D.F. Hoeg; J.E. Forrette; D.I. Lusk
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 149 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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## Abstract A Nβheterocyclic carbene serves as an efficient catalyst for the regioselective ringβopening reactions of aziridines in the presence of acid anhydrides to afford the desired products in good to excellent yields. (Β© WileyβVCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)