The stereospecific loss of water from 1,4-dihydroxy-Δ6,7-octalins under electron impact

✍ Scribed by F. Tureček; A. Vystrčil; V. Hanuš

• Publisher: John Wiley and Sons
• Year: 1977
• Tongue: English
• Weight: 398 KB
• Volume: 12
• Category: Article
• ISSN: 1076-5174
• DOI: 10.1002/oms.1210120104

✦ Synopsis

Abstract

The mass spectra of four of the six 1,4‐dihydroxy‐ Δ^6,7^‐octalins are reported. The spectra differ considerably, depending on the configuration of the hydroxyl groups. The relative amounts of 1‐3,1‐4, transannular 1‐3 and hydroxyl‐hydroxyl elimination of water from the molecular ions were determined by using specificaliy labelled compounds. Effects of configuration and conformation are discussed.