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The stereospecific epoxidation of olefins catalysed by ruthenium

✍ Scribed by G. Balavoine; C. Eskenazi; F. Meunier; H. Rivière

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
223 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

The h&a&&n A hteheunpec&Lc @t b&h CA and Ruthenium oxides are extremely powerful oxidising reagents which have been extensively used in oxidative transformations in organic chemistry'. These reactions involve the use either of a stoechiometric amount of ruthenium tetroxide, or more conveniently of a ruthenium compound in a catalytic quantity with a stoechiometric amount of a readily available oxidant. Many different catalyst-oxidant systems have been described, the most common of which involve RuC13,(H20), as catalyst and hypochlorite or periodate as oxidant. Generally, the reactions are conducted in a two-phase solvent system such asCC14-H20 Recently it has been shown by Sharpless that addition of acetonitrile as a cosolvent gives greatly improved results2.

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