The stereoselective total synthesis of (3R,5R)-sonnerlactone and (3R,5S)-sonnerlactone
β Scribed by Yadav, J.S.; Shiva Shankar, K.; Srinivas Reddy, A.; Subba Reddy, B.V.
- Book ID
- 121816454
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- French
- Weight
- 471 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4039
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The first total synthesis of (3S,4R)-dihydroxy-(6S)-undecyl-a-pyranone 1 and total synthesis of (2S,3R,5S)-(Γ)-2,3-dihydroxytetradecan-5-olide 2 have been achieved in five steps in a highly stereoselective manner using Maruoka allylation, olefin cross-metathesis, and Sharpless asymmetric dihydroxyla