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The stereoselective synthesis of terpene tetrahydrofurans using thallium triacetate

✍ Scribed by Helena M.C. Ferraz; Timothy J. Brocksom; Angelo C. Pinto; Marco A. Abla; Dorothea H.T. Zocher

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 177 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84107-6

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✦ Synopsis

The reaction of diterpenes l-3 and monoterpenes 2, 10 with thallium -triacetate leads stereoselectively to the tetrahydrofuran products 5-7 and 11, --12 respectively, by S-Endo-Trig cyclisation of the 3-alkenol system.

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