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The Stereoisomeric Dibromides and α-Bromo Derivatives of Benzalacetophenone and the Mechanism of Dehydrohalogenation

✍ Scribed by Lutz, Robert E.; Hinkley, David F.; Jordan, Robert H.


Book ID
121015077
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
826 KB
Volume
73
Category
Article
ISSN
0002-7863

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## Abstract The configurational assignment of stereoisomeric 3‐bromo‐3‐acyl derivatives of steroids in both the 5α and 5β series has been carried out by comparing the ^13^C chemical shifts of C‐3. A downfield shift is observed for C‐3, bearing a bromine and an acyl group, on going from the isomer w