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The Stereochemistry of the Hydride Reduction of Some Steroidal Ketones

✍ Scribed by Dauben, William G.; Blanz, Erwin J.; Jiu, James; Micheli, Robert A.

Book ID
127222394
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
563 KB
Volume
78
Category
Article
ISSN
0002-7863

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The reactions of hydrides and Grignard reagents with simple open-chain alaehydes aa ketones I (L, M, S, and R being groups containing carbon and hy- drogen only) are known to lead predominantly to the diastereoisomers IIA, as predicted by "Cram's rule" (1). I ## IIA IIB According to current theo