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The Stereochemistry of the 2,3-Dichloro-p-dioxanes

✍ Scribed by Summerbell, R. K.; Lunk, Hans E.


Book ID
126607664
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
580 KB
Volume
79
Category
Article
ISSN
0002-7863

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Stereochemistry of Dehydrogenation of 1,
✍ Paul Müller; Daniel Joly; François Mermoud 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 438 KB

## Abstract __cis__‐ and __trans__‐(3,6‐D~2~)‐1,4‐cyclohexadienes **1a** and **1b** have been synthesized from __cis__‐3,4‐dichlorocyclobutene (5). Aromatization to benzene with DDQ is __cis__‐stereospecific with an uncertainty of 5%. This result is discussed in relation to concerted or stepwise me