The stereochemistry of chromomycinone and a note on the benzoate rule
โ Scribed by M. Miyamoto; K. Morita; Y. Kawamatsu; K. Kawashima; K. Nakanishi
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 599 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4020
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โฆ Synopsis
Am--It
has been shown that chromomycinom can be rcprescntcd by the absolute con&urationa~ struEtlllt 1. Molecular rotation difkxu between the ratate and benzostc of secondary alcohols can be employed for deriving the rtnolute configuration.
CHROMOMYCI~~ONE (11,' GH,O,,
is the common aglycone of closely related antibiotics, chromomycin A,, A, and A,, the structures of which have recently been elucidated by the present authors .* The stereochemistry of this chromophore will be discussed in this paper.
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