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The stereochemistry of atisine. A chemical correlation of atisine and the resin acids.

โœ Scribed by W.A. Ayer; C.E. McDonald; G.G. Iverach


Book ID
104241974
Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
262 KB
Volume
4
Category
Article
ISSN
0040-4039

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The C-20 epimers of atisine and behavior
โœ S. William Pelletier; Naresh V. Mody ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 201 KB

Atisine (l), an alkaloid of Aconitum heterophyllum Wall, is usually isolated' as the salt, atisinium chloride (2), and can be regenerated from this salt by treatment with strong base. Atisine is a very strong base (pKa 12.8) that may be isamerized easily to isoatisine (3) (pKa 10.3) by refluxing in