✦ LIBER ✦

The stepwise heats of hydrogenation of barrelene, an ab initio study

✍ Scribed by Lawrence R. Schmitz; Norman L. Allinger; Kenneth M. Flurchick

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 601 KB
Volume: 9
Category: Article
ISSN: 0192-8651
DOI: 10.1002/jcc.540090402

No coin nor oath required. For personal study only.

✦ Synopsis

The stepwise heats of hydrogenation of 1 were found to be 38.1,31.8, and 28.4 kcal/mol, respectively. The unusually large heat of hydrogenation for the first double bond is attributed to the destabilizing electronic effects involving the interaction of the three double bonds of 1. 2 1 2 2 2 3 2 4 *Two of us (LRS, KMF) dedicate this paper to our co-author and colleague, Norman L. Allinger, on the occasion of his sixtieth birthday.

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