The statistical mechanics of imperfect polar gases. Part 2.?Dielectric polarization
β Scribed by Buckingham, A. D.; Pople, J. A.
- Book ID
- 121399798
- Publisher
- Royal Society of Chemistry
- Year
- 1955
- Weight
- 304 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0014-7672
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π SIMILAR VOLUMES
INDEX ## Synopsis A statistical theory is given for the refractive index of non polar gases at low densities, taking into account both the effect of statistical fluctuations and the effect of the variation of the polarizability due to molecular interactions. A generalized Lorentz-Lorenz formula i
A quantum mechanical calculation is given for the effect of molecular interactions on the polarizability of spherical non polar molecules in a periodic external electric field. The polarizability tensor is obtained from perturbation theory as a power series in the interaction tensor Tik = Vi vk(l/ri