The static and dynamic conformational properties of cis, cis,trans-1,5,9-cyclododecatriene
β Scribed by Tarik N. Rawdah; M. Zamil El-Faer
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 177 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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The proton spectrum of the isomeric mixture of &,cis-and cis,trans-1,3,5-triamino~clohexane was assigned with a 2D COSY experiment. Using Forrest's modified equation and the 2D J spectrum results, the conformations of the two isomers were analysed. The six-membered ring of the cis,trans isomer is fl
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The con6gurations and conformations of cis-and tram-N-methyl-and -N-benzyl-4,5-and -5,6tetramethylenetetrahydm-l,3-o~es were determined by 'H and -C NMR spectroscopy. The cis isomers are conformationally homogeneous, having the hetero atom attached to the cydohexyl ring, in the axial and equatorial