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The State of the Iron Promoter in Tungstated Zirconia Catalysts

✍ Scribed by Xavier Carrier; Povilas Lukinskas; Stefan Kuba; Lorenzo Stievano; Friedrich E. Wagner; Michel Che; Helmut Knözinger


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
273 KB
Volume
5
Category
Article
ISSN
1439-4235

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The surface structure and atomic composition of triply promoted (KzO/A120,/Ca0) fused iron catalysts, used in the industrial synthesis of ammonia, have been examined by temperature-programmed desorption (i) after having been reduced in hydrogen and (ii) after having synthesised ammonia from a hydrog

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The suggestion, made by Muhler, Nielsen and Fastrup, that the adsorption ofoxygen on to the reduced, triply promoted, fused, iron ammonia-synthesis catalysts would have poisoned the adsorption of molecular nitrogen into the a,, and az states has been examined and has been shown not to be the case. T