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The Standardization of Hydrogen Ion Determinations. I. Hydrogen Electrode Measurements with a Liquid Junction

✍ Scribed by Hitchcock, David I.; Taylor, Alice C.

Book ID
124156249
Publisher
American Chemical Society
Year
1937
Tongue
English
Weight
689 KB
Volume
59
Category
Article
ISSN
0002-7863

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o-Phthalic acid is proposed as a standard substance for buffer solutions of known hydrogen ion concentration (I < 0.2 M KCl, p[H+] = 3.0-5.4, 25Β°C). Its crystallinity, purity and slightly wider buffer range afford advantages over acetic acid. Empirical relationships between measured pH (pH,) and cal